In my opinion Goldfinger is the best. Goldfinger is the epitome of what a James Bond adventure looks like, it contains probably more durable images than any other title in the series: the Aston-Martin tricked out with deadly gimmicks and an ejector seat, the villain Goldfinger, the mute Korean assassin and who can forget that dead woman covered head to toe in gold? Plus there is Sean Connery at his best.
Ooh tough choice. Sean Connery was, in my opinion, the best Bond. I thoroughly enjoyed all of the Bond films he did, however I would have to say that it's a tie between "From Russia With Love" and "Diamonds Are Forever". "Goldfinger" and "Dr. No" both deserve mention as well, but I found that the 'Bond formula' were truly perfected in "Diamonds Are Forever" and that the earlier films, especially "From Russia With Love", focused more on the plot and the intrigue than on the gadgets and wisecracks, which to me made it feel more legitimate as a spy thriller.
uh....wow, um I loved "From Russia With Love" and "Goldfinger" I mean you just can't go wrong with Sean Connery. Now someone might shoot me for saying this but I really like "Goldeneye" with Pierce Bronson. The plot does get gimmicky at times what with Boris, but the whole Alec Trevelyan character really brings it together for me. Honestly I don't care for Daniel Craig's James Bond at all. Sure he does a great character, but the plot isn't there for me, and he just doesn't seem to fit.
I like James Bond movies and I think the best ones were Goldfinger, Tomorrow Never Dies and Die Another Day. I personally think that Quantum of Solace was not so good.